You just need to click the foreground icon in the Tools palette. That will bring up the color picker. Select a color in the box, or move onto the layout to use the resulting "eye dropper" icon to pick a color off your page.
The foreground/background icons are the black/white overlapping squares at the bottom of the Tools palette on the left side of your workspace.
HTH!
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Cassie
My Gear: Nikon D300s w/18-200mm VR & 50mm 1.4
Software: Adobe Photoshop CS4, PSE 6, Lightroom 2
 
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