I tried many things, but in the end, to sum it up, I think you just have to play around with the photo until you get the right size (100 x 100 and save for web at 72dpi), and then you have to change it in BOTH your profile as well as User CP and make sure your cache is cleared.
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My Gallery
Cameras: Canon Rebel XS DSLR and Canon Power Shot SD900 Digital Elph point-n-shoot
Software: PSE8 and Lightroom 2
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